Study of the thermal decomposition of 2,2’,4,4’,6,6’- hexanitrostilbene
Journal Of Aerospace Technology And Management
Endereço:
Pr Mal Eduardo Gomes, 50
São José dos Campos / SP
Site: http://www.jatm.com.br
Telefone: (12) 3947-5115
ISSN: 19849468
Editor Chefe: Francisco Cristóvão Lourenço de Melo
Início Publicação: 31/05/2009
Periodicidade: Quadrimestral
Área de Estudo: Engenharia aeroespacial
Study of the thermal decomposition of 2,2’,4,4’,6,6’- hexanitrostilbene
Ano: 2010 | Volume: 2 | Número: 1
Autores: Gilson da Silva, Koshum Iha, Andreza M. Cardoso, Elizabeth C. Mattos, Rita de Cássia L.Dutra
Autor Correspondente: Gilson da Silva | [email protected]
Autor Correspondente: Gilson da Silva | [email protected]
Palavras-chave: explosives, hns, dsc, ft-ir
Resumos Cadastrados
Resumo Inglês:
2,2’, 4,4’, 6,6’- hexanitrostilbene (HNS) is an energetic material, a nitroaromatic compound, with thermal and chemical stabilities, which is employed in the aerospace industry. In this work, the Arrhenius parameters (activation energy and pre-exponential factor) of thermal decomposition reaction were studied and the results were compared with the values reported in the literature. The Kissinger method, applied to DSC’s non-isothermal data of the decomposition temperature was chosen for this study. The activation energy determined for the thermal decomposition of HNS revealed values from 428 kJ.molˉ¹ to 477 kJ.molˉ¹, under the experimental conditions employed.