Degradation dynamics of an oxime carbamate insecticide (methomyl) in aqueous medium of varying pH under laboratory simulated condition

Orbital: The Electronic Journal of Chemistry

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ISSN: 19846428
Editor Chefe: Adilson Beatriz
Início Publicação: 28/02/2009
Periodicidade: Trimestral
Área de Estudo: Química

Degradation dynamics of an oxime carbamate insecticide (methomyl) in aqueous medium of varying pH under laboratory simulated condition

Ano: 2010 | Volume: 2 | Número: 3
Autores: Md. Wasim Aktar, Samsul Alam, Dwaipayan Sengupta, Ashim Chowdhury
Autor Correspondente: Dwaipayan Sengupta | [email protected]

Palavras-chave: methomyl, ph, dissipation, kinetics, insecticide

Resumos Cadastrados

Resumo Inglês:

Laboratory degradation studies were performed in water at pH 4.0, 7.0 and
9.2 using methomyl (Lannate 12.5 L) formulation at the rates of 1.0 (T1) and 2.0 (T2)
μgmL
-1
. Water samples collected on 0 (2 h), 3, 7, 15, 30, 45, 60 and 90 days after
treatments were processed for residue analysis of methomyl by HPLC equipped with
Photo Diode Array Detector. In 60 days, dissipation was 84-87% at pH 4.0, 71-77% at
pH 7.0, and 91-93% at pH 9.2 in both treatments showing very little effect of pH on
dissipation. The half-life periods observed were 20.76 and 22.13 days at pH 4.0, 27.87
and 28.67 days at pH 7.0 and 15.84 and 16.54 days at pH 9.2 at T1 and T2 doses
respectively.