Derivative spectrophotometric determination of uranium (VI) using diacetyl monoxime isonicotinoyl hydrazone (DMIH)

Orbital: The Electronic Journal of Chemistry

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ISSN: 19846428
Editor Chefe: Adilson Beatriz
Início Publicação: 28/02/2009
Periodicidade: Trimestral
Área de Estudo: Química

Derivative spectrophotometric determination of uranium (VI) using diacetyl monoxime isonicotinoyl hydrazone (DMIH)

Ano: 2011 | Volume: 3 | Número: 1
Autores: Gadikota ChandraSekhar Reddy, N. Devanna, K. B. Chandrasekhar
Autor Correspondente: Gadikota ChandraSekhar Reddy | [email protected]

Palavras-chave: diacetyl monoxime isonicotinoyl hydrazone (dmih), derivative spectrophotometry, uranium (vi)

Resumos Cadastrados

Resumo Inglês:

Uranium (VI) forms a yellow coloured water soluble complex with diacetyl monoxime isonicotinoyl hydrazone (DMIH) reagent in acidic buffer of pH 3.25 with λmax at 364 nm. The molar absorptivity and sandell’s sensitivity are 1.63 X 104 L.mol-1.cm-1 and 0.00307692 µg/cm2, respectively. The Beer’s law validity range is 1.19–14.28 µg/mL. Uranium (VI) forms (M:L) 1:1 complex with DMIH and stability constant of the complex is 4.928 X 106.The derivative spectrophotometric determination of U (VI) was carried out by measuring peak height method. The developed derivative spectrophotometric method was employed for the determination of uranium (VI) in rock and synthetic samples. The effect of various diverse ions was also studied.