Pyrazine carboxylic acid derivatives of dichlorobis(cyclopentadienyl)titanium (IV)

Orbital: The Electronic Journal of Chemistry

Endereço:
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ISSN: 19846428
Editor Chefe: Adilson Beatriz
Início Publicação: 28/02/2009
Periodicidade: Trimestral
Área de Estudo: Química

Pyrazine carboxylic acid derivatives of dichlorobis(cyclopentadienyl)titanium (IV)

Ano: 2012 | Volume: 4 | Número: 2
Autores: Satish Chandra Dixit, Rohit Kumar Singh
Autor Correspondente: Satish Chandra Dixit | [email protected]

Palavras-chave: Cp2TiCl2, tumour, complexes, characterization, synthesis, pyrazine carboxylic acids

Resumos Cadastrados

Resumo Inglês:

Reactions of dichlorobis(cyclopentadienyl)titanium (IV) with pyrazine carboxylic acids viz. 2-pyrazine carboxylic acid (2-PzCH), 5-methyl-2-pyrazine carboxylic acid (MPzCH) and 2,3-pyrazine dicarboxylic acid (2,3-PzDCH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Ti(2-PzC)Cl, Cp2Ti(2-PzC)2, Cp2Ti(MPzC)Cl,Cp2Ti(MPzC)2, Cp2Ti(2,3-PzDCH)Cl and Cp2Ti(2,3-PzDCH)2 were obtained. These newly synthesized complexes were characterized on the basis of elemental analyses, electrical conductance, magnetic moment and spectral data.