Supported nano gold a recyclable catalyst for green, solvent free, selective and efficient oxidation of alcohol using molecular oxygen

Orbital: The Electronic Journal of Chemistry

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Site: http://www.orbital.ufms.br
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ISSN: 19846428
Editor Chefe: Adilson Beatriz
Início Publicação: 28/02/2009
Periodicidade: Trimestral
Área de Estudo: Química

Supported nano gold a recyclable catalyst for green, solvent free, selective and efficient oxidation of alcohol using molecular oxygen

Ano: 2011 | Volume: 3 | Número: 2
Autores: Bashir Ahmad Dar, Mazahar Farooqui
Autor Correspondente: Bashir Ahmad Dar | [email protected]

Palavras-chave: ceria-silica, ceria-titania, ceria-zirconia, ceria-alumina, gold supported catalyst, catalytic oxidation

Resumos Cadastrados

Resumo Inglês:

The myth that gold cannot act as a catalyst has been discarded in view of recent studies, which have demonstrated the high catalytic efficiency of pure nano-gold and supported nano-gold catalysts. In recent years, numerous papers have described the use of supported nano-gold particles for catalysis in view of their action on CO and O2 to form CO2, as well as a variety of other reactions. Special emphasis is placed on the oxidation studies undertaken on model nano-Au systems. In this work a solvent free oxidation of 1-phenyl ethanol was carried out using gold supported on ceria-silica, ceriatitania, ceria- zirconia and ceria-alumina at 160 0C. Almost 88-97% conversion was obtained with >99% selectivity. Temperature screening was done from 70 to 160 0C.Catalysts were prepared by deposition co-precipitation method and deposition was determined by EDEX analysis.